Samuel Chukwueze was an unused substitute as Villarreal recorded a hardfought 3-2 win at Atalanta in Group F, and qualify for the round of 16, Completesports.com reports.
The game was shifted to Thursday no thanks to heavy snow which was experienced on Wednesday.
A brace from Arnaut Danjuma and a goal from Etienne Capoue, saw Villarreal clinch the final round of 16 ticket.
The result means Villarreal join Manchester United (leaders in Group F) in the next round.
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